Copper(II)-catalyzed highly regio- and stereo-selective hydrosilylation of unactivated internal alkynes with silylborate in water.
نویسندگان
چکیده
The highly regio- and stereoselective hydrosilylation of internal alkynes with silylborate catalyzed by Cu(OTf)2 with 1,10-phenanthroline as the ligand in the presence of Cs2CO3 in water is developed. This protocol was applied efficiently in the aqueous synthesis of multi-substituted vinylsilanes.
منابع مشابه
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عنوان ژورنال:
- Organic & biomolecular chemistry
دوره 13 21 شماره
صفحات -
تاریخ انتشار 2015